Metal oxide/hydroxide particles coated with phosphate esters

Catalyst – solid sorbent – or support therefor: product or process – Solid sorbent – Having specifically intended extraneously added iron group...

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55 67, 2101982, 2101983, 210656, 427220, 428403, 502 7, 502401, 502407, 502415, B01J 2004, B01J 2032, B01D 1508, B32B 900

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active

049295896

ABSTRACT:
An active material is disclosed comprising metal oxide/hydroxide particles having chemically bonded to reactive sites on a surface thereof, a monolayer of a phosphorous-containing organic material comprised of a phosphorous-containing group and a carbon-containing group. The bond to the metal oxide/hydroxide particle surface is formed by reaction of the phosphorous-containing group with the metal oxide/hydroxide particle surface, so that the carbon-containing group of the material is oriented away from the metal oxide/hydroxide surface.

REFERENCES:
patent: 4382016 (1983-05-01), Rickelton et al.
patent: 4786628 (1988-11-01), Wieserman et al.
patent: 4788176 (1988-11-01), Wieserman et al.
"Selective Retention of Organic Phosphate Esters & Phosphonates on Aluminum Oxide"-Coletti-Previero et al., Bioscience Reports-vol. 6, No. 5, 1986-pp. 477-483.
"The Adsorption of Di-N-Butylphosphate on Alumina from Organic Solutions on Some Metal Oxides"-Gal et al., J. Inorg. Nucl. Chem., -vol. 25, 1964-pp. 129-130.

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