Metal on plastic films with adhesion-promoting layer

Stock material or miscellaneous articles – All metal or with adjacent metals – Composite; i.e. – plural – adjacent – spatially distinct metal...

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20419215, 20419216, 20419227, 359584, 359585, 359839, 428627, 428660, 428662, 428663, 428687, 428458, 428469, 428480, 4289122, 428913, C23C 1400, G02B 110, B32B 1508, B32B 900

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055892809

ABSTRACT:
The adhesion to plastic substrates of thick layers of functional metals having an oxide heat of formation that is greater than -40,000 calories/gram atom of metal, such as silver, copper, gold, and the like, is improved if a thin layer of a metal having an oxide heat of formation of less than -50,000 calories/gram atom of metal is present as an adhesion-promoting primer layer. When the primer layer metal has a melting point greater than 1100.degree. C., it should be present as the metal or as a substoichiometric oxide. When the primer layer metal has a melting point less than 1100.degree. C., it may be present as the metal, as a substoichiometric oxide, or as a full stoichiometric oxide. Processes for preparing these materials using sputter-depositing and reflectors incorporating these materials are also disclosed.

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Hass, George, et al., eds., Physics of Thin Films: Advances in Research and Development; Academic Press, NY, (1982) 12:36-39.

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