Metal extraction process using quaternary ammonium thiocyanates

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group ib metal

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423100, 423139, C01G 300, C01G 900, C01G 5100, C01G 5300

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039767426

ABSTRACT:
An improvement in the process of extracting metal from aqueous acidic solution using a quaternary ammonium thiocyanate extractant wherein a special amount of thiocyanate ion is introduced into the aqueous solution prior to or contemporaneously with the extraction. Results achieved are better extractions with little or no additional loss of thiocyanate ion in the aqueous raffinate.

REFERENCES:
patent: 3194652 (1965-07-01), Clifford et al.
Wilson et al., Analytical Chemistry, vol. 35, No. 3 Mar. 1963 pp. 302-307.
Moore, F. L., Analytical Chemistry, vol. 36, No. 11, Oct. 1964 pp. 2158-2162.
Chemical Abstracts vol. 59, No. 2221e.
Chemical Abstracts vol. 61 (1964) No. 7680h.
Analytica Chimica Acta. 38 (1967) pp. 547-552.
Journal of Chromatography 53(1970) pp. 345-353.

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