Metal-doped organic gels and method thereof

Colloid systems and wetting agents; subcombinations thereof; pro – Continuous or semicontinuous solid phase – The solid phase contains organic material

Reexamination Certificate

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C516S098000, C516S099000, C521S153000, C521S180000, C521S181000, C977S773000

Reexamination Certificate

active

10457131

ABSTRACT:
Disclosed herein is a sol-gel polymerization process for synthesizing metal-doped organic gels. The process polymerizes metal salts of hydroxylated benzenes or hydroxylated benzene derivatives with alkyl or aryl aldehydes to form metal-doped, wet, organic gels. The gels can then be dried by supercritical solvent extraction to form metal-doped aerogels or by evaporation to form metal-doped xerogels. The aerogels and xerogels can then be pyrolyzed.

REFERENCES:
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patent: 5395805 (1995-03-01), Droege et al.
Maldonado-Hódar et al., Catalytic Graphitization of Carbon Aerogels by Transition Metals, Langmuir, 2000, 16, 4367-4373.
E. Bekyarova et al., Structure and Physical Properties of Tailor-Made Ce, Zr-Doped Carbon Aerogels, Advanced Materials, vol. 12, No. 21, 2000, 1625-1628.
R. W. Pekala et al., Organic aerogels from the polycondensation of resorcinol with formaldehyde, J. Mater. Sci., 1989, 24, 3221-3227.
Organic Aerogels from the Polycondensation of Resorcinol with Formaldehyde, R.W. Pekala, Material Science, journal vol. 24, pp. 3221-3227.

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