Metal complexes useful as rubber/metal bonding promoters

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524 83, 556139, B32B 1506

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active

046542710

ABSTRACT:
Compounds containing an organic thiosulphate anion and cationic nickel or cobalt in association with an amine, are useful in increasing the bond strength between metal, especially brass, and vulcanized rubber. Typical complexes are those where the anion is dodecylthiosulphate or hexamethylenebis(thiosulphate), and the amine is ethylenediamine or N-benzyl-N-t-octylamine.

REFERENCES:
patent: 2936295 (1960-05-01), Brodkey et al.
patent: 3036034 (1962-05-01), Rumscheidt
patent: 3535249 (1970-10-01), Larson
patent: 3732192 (1973-05-01), Arnold
patent: 3869435 (1975-05-01), Trivette
patent: 4417012 (1983-11-01), Moniotte
A. S. Foust et al. article Inorg. Chem. 1980, 19, 1048-1050, "Preparation and Structure of the Bunte Salt Trans-Dichlorobis(Ethylenediamine) Cobalt (III) S-Hydroxymethyl Thiosulfate".

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