Metal complexes of bis-azomethines from hydroxy-aldehydes and al

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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106193P, 106241, 106288Q, 260 25HK, 260 37R, 260429C, 2604299, 260439R, C07F 108

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040440362

ABSTRACT:
1:1 metal complexes of bis-azomethines of the formula ##STR1## wherein R denotes an alkylene radical which contains 2-8 C atoms and is optionally interrupted by hetero-atoms, X denotes a H or halogen atom or an alkyl, alkoxy, carboxyl, alkoxy-carbonyl or phenylazo group and Y and Z denote H or halogen atoms, or wherein the substituents Y and Z form a fused benzene ring, if R contains a hetero-atom, Y and Z must not be H atoms, and if R contains 2 C atoms, X, Y and Z must not be H atoms, and a metal are valuable pigments coloring plastics and printing inks in fast yellow to range shades.

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Martell et al., Chemistry of the Metal Chelate Compounds, Prentice-Hall, Inc., N.Y., pp. 17, 69, 70, 140, 214-216, 228, 269, 271, 274, 289, 291, 292, 338 (1952).
Dwyer et al., Chelating Agents and Metal Chelates, Academic Press, N.Y., pp. 167, 168, 170 to 173, 177 to 181 (1964).
Bailar, The Chemistry of the Coordination Compounds, Reinhold Publ. Corp., N.Y., pp. 46, 235, 236, 259, 260, 287, 321, 391 (1956).
J.A.C.S., vol. 66, pp. 952, 2267, 2268 (1946).

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