Metal carbonate initiator and method for polymerizing...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

Reexamination Certificate

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C528S048000, C562S459000, C562S460000, C502S150000, C502S161000, C502S172000

Reexamination Certificate

active

07622540

ABSTRACT:
Disclosed herein is a metal enolate initiator for polymerizing isocyanates and a method for polymerizing isocyanates by anionic polymerization using the same, in which the initiator forms a cluster upon the initiation and protects stability of terminal anions at the end of the chain to cause controlled polymerization, thus preventing depolymerizaton and improving reaction time and efficiency without the use of a separate additive.

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Patten, et al., “Organotitanium(IV)-Catalyzed Cyclopolymerizations of 1,2-Diisocyanates and Cyclocopolymerizations of Monoisocyanates with 1,2-Diisocyanates,” Macromolecules, vol. 29, No. 18, pp. 5882-5892 (1996).
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