Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2006-09-12
2006-09-12
Harlan, Robert D. (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C526S282000, C526S308000, C526S240000, C546S002000
Reexamination Certificate
active
07105617
ABSTRACT:
This invention relates to the synthesis of Mqn-containing monomeric compounds, comprising a polymerizable moiety, an Mqn-moiety, and an optional chemical spacer therebetween, wherein q, in each instance, comprises an 8-hydroxyquinoline residue, M is a metal such as Mg, Zn, Al, Ga, or In, and n is 2 or 3 as the valence of the metal requires. For example, the polymerization of Znq2- or Alq3-containing monomers, in the presence or absence of a co-monomer, provided a Znq2- or Alq3-containing polymer, which retained the optical properties of Znq2or Alq3in solution, respectively. The Mqn-containing polymers may be used in, among other things, the fabrication of light-emitting diodes (LEDs).
REFERENCES:
patent: 5141671 (1992-08-01), Bryan et al.
patent: 5719467 (1998-02-01), Antoniadis et al.
patent: 6228436 (2001-05-01), Affinito
patent: 2002/0028350 (2002-03-01), Toguchi et al.
patent: 2002/0032288 (2002-03-01), Tanaka et al.
patent: 0992564 (2000-04-01), None
patent: 1000998 (2000-05-01), None
patent: 09255686 (1997-03-01), None
patent: 09316441 (1997-12-01), None
patent: 10053759 (1998-02-01), None
patent: 2000021573 (2000-01-01), None
patent: 2001284052 (2001-10-01), None
patent: WO 03/044878 (2003-05-01), None
patent: WO 03/048268 (2003-06-01), None
Burrows et al., Appl. Phys. Lett. 64 (20) (May 15, 1994).
Meyers et al., Macromolecules 2003, 36, 1766-68.
Lu et al., Journal of Polymers : Part A : Polymer Chemistry, vol. 38 2887-2892 (2000).
Meyers et al., Chem Mater. 2004 16 1183-1188.
Burroughes et al., Nature 347, 539-541 (Oct. 11, 1990).
Takeshi Tominaga et al., “Luminescent Component”, XP002287238, STN Database Accession No. 2001: 778307 Abstract, JP 2001 297881, October 26, 2001, Chemical Abstracts Service, Columbus, Ohio.
Shuji Iwasaki et al., “Zinc Complex and Organic Electroluminescent (EL) Device Using the Complex”, XP002287239, STN Database Accession No. 2001: 573264 Abstract, JP 2001 213866, Aug. 7, 2001, Cheamical Abstracts Service, Columbus, Ohio.
Hodaka Tsuge et al., “Organic Electroluminescent Component”, XP002287240, STN Database Accession No. 2000: 638398 Abstract, JP 2000 252072, Sep. 14, 2000, Chemical Abstracts Service, Columbus, Ohio.
Takeshi Tominaga et al., “Electroluminescent Component”, XP002287241, STN Database Accession No. 2000:274718 Abstract, JP 2000 123972, Apr. 28, 2000, Chemical Abstracts Service, Columbus, Ohio.
Kido, Junji et al., “Orange Color Electroluminescence from Bis (2-styryl-8-Quinolinolato)zinc(II)”, Chemistry Letters 1997, The Chemical Society of Japan, 1997.
Zhongmin, Su et al., “Electronic Property and Molecule Design for Luminescent Metal Complexes of Tris(8-Hdyroxquinoline) Gallium”, XP009033203 Science in China, Series B: Chemistry, vol. 43, No. 6, Dec. 2000.
Raj, D.S., “Coordination Polymers Based on Bis-Ligand: 1,7-DI(8-Hydroxy-5-Quinolinyl)AZA-1, 3, 5-Heptatriene-3-OL(DHQAHT)”, XP009033212, Oriental Journal of Chemistry, vol. 17, No. 3, 2001.
Meyers, Amy et al., “Design and Synthesis of Alq3-Functionalized Polymers”, XP002287215, vol. 36, No. 6, American Chemical Society, pp. 1766-1768, 2003.
Duann, Yeh-Fang et al., “The Characteristic of Photoluminescence of tris-(7-Substituted-8-Hydroxyquinoline) Aluminum Complexes and Polymeric Complexes”, XP009033202, Applied Organometallic Chemistry, vol. 17, pp. 952-957, 2003.
Meyers, Amy et al., “Solution and Solid-State Characterization of Alq3-Functionalized Polymers”, XP002287214, Chemistry of Materials, vol. 16, No. 7, pp. 1183-1188, 2004.
Chemical Journal of Chinese Universities, XP009033211, vol. 21, No. 9, pp. 1416-1421, Sep. 9, 2000.
Chen, C.H. et al., “Metal Chelates as Emitting Materials for Organic Electroluminescence”, Coordination Chemistry Reviews 171, pp. 161-174, 1998.
Sheats, James R. et al., “Organic Electroluminescent Devices”, Science, New Series, vol. 273, No. 5277, pp. 884-888, Aug. 16, 1996.
Tang, C.W. et al., “Organic Electroluminescent Diodes”, Appl. Phys. Lett. 51, pp. 913-915, Sep. 21, 1987.
Tang,C.W. et al., “Electroluminescence of Doped Organic Thin Films”, J. Appl. Phys. 85 (9), pp. 3610-3616, May 1, 1989.
Sheats, James R., “Stacked Organic Light-Emitting Diodes in Full Color”, Science, New Series, vol. 277, No. 5323, pp. 191-192, Jul. 11, 1997.
Jianping, Lu et al., “Synthesis and Characterization of a Novel AlQ3-Containing Polymer”, Journal of Polymer Science: Part A: Polymer Chemistry, vol. 38, pp. 2887-2892, 2000.
Jang, Hyosook et al., “Synthesis and Characterization of New Luminescent Materials Containing Various Substituted 8-Quinolinolate”, Synthetic Metals 121, pp. 1667-1668, 2001.
Hopkins, T.A et al., “Substituted Aluminum and Zin Quinolates with Blue-Shifted Absorbance/Luminescence Bands:Synthesis and Spectroscopic, Photoluminescense, and Electroluminescence Characterization”, American Chemical Society, vol. 8, pp. 344-351, 1996.
Colle, Michael et al. “Preparation and Characterization of Blue-luminescent Tris(8-hydroxyquinoline) Aluminum (Alq3)”, Advanced Functional Materials, vol. 13, No. 2, pp. 108-112, Feb. 2003.
Brinkmann, Martin et al., “Correlation Between Molecular Packing and Optical Properties in Different Crystalline Polymorphs and Amorphous Thin Films of mer-Tris(8-Hydroxyquinoline)Aluminum(III)”, American Chemical Society, vol. 122, pp. 5147-5157, 2000.
Braun, M. et al., “A New Crystalline Phase of the Electroluminescent Material Tris(8-hydroxyquinoline) Aluminum Exhibiting Blueshifted Fluorescence”, Amerian Institue of Physics, vol. 114, No. 21, pp. 9625-9632, Jun. 1, 2001.
Fischer, Hanns, “The Persistent Radical Effect: A Principle for Selective Radical Reactions and Living Radical Polymerizations”, American Chemical Society, vol. 101, pp. 35 81-3610, Nov. 7, 2001.
Hawker, Craig J. et al., “New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations”, American Chemical Society, vol. 101, pp. 3661-3688, Oct. 25, 2001.
Kamigaito, Masami et al., “Metal-Catalyzed Living Radical Polymerization”, American Chemical Society, vol. 101, pp. 3689-3745, Dec. 12, 2001.
Buchmeiser, Michael R., “Homogeneous Matathesis Polymerization by Well-Defined Group VI and Group VIII Transition-Metal Alkylidenes: Fundamental and Applications in the Preparation of Advanced Materials”, American Chemical Society, vol. 100, pp. 1565-1604, Mar. 16, 2000.
Hawker, Craig J, “Living” Free Radical Polymerization: A Unique Technique for the Preparation of Controlled Macromolecular Architectures, Accounts of Chemical Research, vol. 30, No. 9, pp. 373-382, Mar. 18, 1997.
Sapochak, Linda S. et al, “Electroluminescent Zinc(II) Bis(8-hydroxquinoline): Structural Effects on Electronic States and Device Performance”, American Chemical Society, vol. 124, No. 21, pp. 6119-6125, Feb. 5, 2002.
Sapochak, Linda S. et al., “Effects of Systematic Methyl Substitution of Metal (III)Tris(n-Methyl-8-Quinolinolato) Chelates on Material Properties for Optimum Electroluminescence Device Performance”, American Chemical Society, vol. 123, No. 26, pp. 6300-6306, Jun. 9, 2001.
Stubbs, Ludger P. et al., “Towards a Unviersal Polymer Backbone: Design and Synthesis of Polymeric Scaffolds Containing Terminal Hydrogen-Bonding Recognition Motifs at Each Repeating Unit”, Chemistry A European Journal, vol. 9, No. 4, pp. 992-999, 2003.
Meyers Amy
Weck Marcus
Georgia Tech Research Corporation
Harlan Robert D.
Womble Carlyle Sandridge & Rice PLLC
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