Mesoporous silica and process for producing the same

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

Reexamination Certificate

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Reexamination Certificate

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10716427

ABSTRACT:
(A) An anionic surfactant, (B) a silicate monomer and (C) a basic silane are mixed in water or a mixed solvent of a water-miscible organic solvent and water to obtain a mesoporous silica complex having mesopores with a uniform size, the anionic surfactant Component (A) is removed by washing the resultant mesoporous silica complex with an acidic aqueous solution, a water-miscible organic solvent or an aqueous solution thereof to obtain a mesoporous silica outer shell utilizing the structure of the mesoporous silica complex as a template, and the mesoporous silica complex or the mesoporous silica outer shell is calcined to obtain a mesoporous silica. The mesoporous silica can be synthesized in this manner utilizing the anionic surfactant micelle with a remarkably low affinity to the silicate monomer.

REFERENCES:
patent: 5858457 (1999-01-01), Brinker et al.
Template-directed synthesis of bi-functionalized organo-MCM-41 and phenyl-MCM-48 silica mesophases Simon R. Hall, Christabel E. Fowler Benedicte Lebeau and Stephen Mann Chem. Commun., 1999,201-202.

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