Meso-substituted tripyrrane compounds, compositions, and methods

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

548518, 548519, 548520, 548521, 548522, 548527, 5462681, C07D48722, C07D40306

Patent

active

059199237

ABSTRACT:
The invention provides for tripyrrane compounds of the formula ##STR1## wherein: each Q represents, typically, an alkyl group, cycloalkyl group, aryl group, or a heteroaryl group; and each R represents hydrogen, an alkyl group, alcohol group, or a carbonyl-containing group. Additionally, there are described methods to prepare such compounds, for example, comprising the steps of:

REFERENCES:
patent: 4935498 (1990-06-01), Sessler et al.
patent: 5159065 (1992-10-01), Sessler et al.
patent: 5162509 (1992-11-01), Sessler et al.
patent: 5182348 (1993-01-01), Braeunling et al.
patent: 5302714 (1994-04-01), Sessler et al.
patent: 5599948 (1997-02-01), Wijesekera
patent: 5674467 (1997-10-01), Maier et al.
patent: 5756726 (1998-05-01), Hemmi et al.
Lee et al. Tetrahedron, vol. 50, No. 39 1994 pp. 11427-11440.
Bauer, V.J. et al., "Sapphyrins: Novel Aromatic Pentapyrrolic Macrocycles," J. Am. Chem. Soc. (1983) 105:6429-6436.
Berlin, K. et al., "New Porphyrinoid Macrocycles Containing Pyridine," Angew. Chem. Int. Ed. Engl. (1994) 33(2):219-220.
Berlin, K. et al., "Benziporphyrin, a Benzene-Containing, Nonaromatic Porphyrin Analogue," Angew. Chem. Int. Ed. Engl. (1994) 33(12):1246-1247.
Broadhurst, M.J. et al., "The Synthesis of 22 .pi.-Electron Macrocycles. Sapphyrins and Related Compounds," Journal of the Chemical Society (1981) 16:2111-2116.
Cavaleiro, J.A.S. et al., "An Anomalous Dipyrrole Product from Attempted Synthesis of a Tetraarylporphyrin," J. Org. Chem. (1988) 53:5847-5849.
Charriere, R. et al., "The Chemistry of Polyphrins 2..sup.1 Synthesis of Hexaphyrins and Their Metal Complexes," Heterocycles (1993) 36(7):1561-1575.
Chmielewski, P.J. et al., "Tetra-p-tolylporphyrin with an Inverted Pyrrole Ring: A Novel Isomer of Porphyrin" Angew. Chem. Int. Ed. Engl. (1994) 33(7):779-781.
Chmielewski, P.J. et al., "5,10,15,20-Tetraphenylsapphyrin--Identification of a Pentapyrrolic Expanded Porphyrin in the Rothemund Synthesis," Chem. Eur. J. (1995) 1(1):68-73.
Furuta, H. et al., "`N-Confused Porphyrin`: A New Isomer of Tetraphenylporphyrin," J. Am. Chem. Soc. (1994) 116:767-768.
Hill, C.L. et al., "Isolation and Characterization of the Principal Kinetic Product in the Preparation of a Sterically Hindered Tetra-arylporphyrin: X-Ray Structure of a Bis(dipyrromethene) Complex of Zinc, Zn.sup.11 (C.sub.22 H.sub.13 Cl.sub.4 N.sub.2).sub.2 .cndot.toluene" J. Chem. Soc., Chem. Commun. (1985):1228-1229.
Lee, C-H. et al., "One-Flask Synthesis of Meso-Substituted Dipyrromethanes and Their Application in the Synthesis of Trans-Substituted Porphyrin Building Blocks," Tetrahedron (1994) 50(39):11427-11440.
Rexhausen, H. et al., "The Synthesis of a New 22 .pi.-Electron Macrocycle: Pentaphyrin," J. Chem. Soc., Chem. Commun. (1983):275.
Sessler, J.L. et al., "Sapphyrins and Heterosapphyrins," Tetrahedron (1992) 48(44):9661-9672.
Sessler, J.L. et al., "Synthesis and Crystal Structure of a Novel Tripyrrane-Containing Porphyrinogen-like Macrocycle," J. Org. Chem. (1987) 52:4394-4397.
Sessler, J.L. et al., "Texaphyrins: Synthesis and Applications," Acc. Chem. Res. (1994) 27:43-50.
Sessler, J.L. et al., "A Nonaromatic Expanded Porphyrin Derived from Anthracene--A macrocycle which Unexpectedly Binds Anions," Angew. Chem. Int. Ed. Engl. (1992) 31(4):452-455.
Shipps, G., Jr. et al., "New Synthetic Receptors Derived from Porphyrins," Tetrahedron Letters (1994) 35(37):6823-6826.
S. Vigmond et al., "Direct Synthesis of Aryldipyrromethanes," Tetrahedron Letters, vol. 35, pp. 2455-2458, 1994.
P-Y. Heo et al., "Facile Syntheses of Modified Tripyrranes and Their Application to the Syntheses of Regioisomerically Pure Porphyrin Derivatives," Bulletin of the Korean Chemical Society, 17, pp. 515-521 1996.
Chemical Abstracts, vol. 125, No. 11 (1996), Abstract No. 142406.
Tetrahedron Letter, vol. 37(2), pp. 197-200, "Stepwise Synthesis of Core-Modified, Meso-Substituted Porphyrins".
Tetrahedron Letter, vol. 35(16), pp. 2455-2458, "Direct Synthesis of Aryldipyrromethanes".
Thomas Carrell, "Modellverbinungen zur Untersuchung der Primaprozesse in der Photosynthese" Doctoral Disseration, Ruprecht-Karls Universistat, Heidelberg, Germany, 1992.
Sessler et al, Chem. Eur. J., vol. 1, No. 1, 1995, pp. 56-67.
Broadhurst et al, J.C.S. Perkin, I pages 2111-2116 (1972).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Meso-substituted tripyrrane compounds, compositions, and methods does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Meso-substituted tripyrrane compounds, compositions, and methods, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Meso-substituted tripyrrane compounds, compositions, and methods will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-900064

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.