Mercury monitoring system and calibration

Measuring and testing – Instrument proving or calibrating – Gas or liquid analyzer

Reexamination Certificate

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Details

C073S001060, C073S001070, C073S031050, C422S083000, C422S093000, C436S081000

Reexamination Certificate

active

07454945

ABSTRACT:
A calibration assembly generates elemental mercury and oxidized mercury for calibrating components of a mercury monitoring system, including making necessary adjustments to efficiencies of a mercury compound converter and an elemental mercury detector. The calibrator generates an elemental mercury sample having a known elemental mercury concentration, [Hg0]1and combines an oxidizing component with the elemental mercury sample, thereby producing a reduced concentration of elemental mercury [Hg0]2within the sample. The calibrator measures the concentration of elemental mercury [Hg0]2within the sample and calculates a difference between the known elemental mercury concentration, [Hg0]1and the reduced concentration [Hg0]2. The difference between [Hg0]1and [Hg0]2is substantially equal to the concentration of oxidized mercury produced by the calibrator. The concentration of oxidized mercury can also be calculated as the difference between elemental mercury detected after passing a sample stream containing oxidized mercury through a channel which includes the converter and the reduced concentration [Hg0]2detected after passing the sample stream through a channel which bypasses the converter. By providing oxidized mercury at calculated concentrations, the calibrator allows a user to calibrate continuous emission monitoring systems for accurate response to both elemental mercury and oxidized mercury.

REFERENCES:
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patent: 6690462 (2004-02-01), Seltzer
patent: 6830730 (2004-12-01), Rhodes
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patent: 2003/0103206 (2003-06-01), Seltzer
patent: 2005/0061110 (2005-03-01), Schaedlich et al.

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