Membrane made from a multi-block polymer comprising an imide or

Liquid purification or separation – Processes – Liquid/liquid solvent or colloidal extraction or diffusing...

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Details

210650, 210651, 210653, 21050039, 525113, B01D 6136

Patent

active

050394177

ABSTRACT:
The present invention is directed to a multi-block polymeric material comprising an imide prepolymer chain extended with a second, different, compatible prepolymer selected from the group of prepolymers comprising (a) an (A) dianhydride or its corresponding tetraacid or diacid - diester combined with a monomer selected from (B) epoxy, diisocyanate, polyester and diamine in an A/B mole ratio ranging from about 2.0 to 1.05, preferably about 2.0 to 1.1 and (b) an (A) diamine combined with a monomer selected from (B) epoxy, diisocyanate and dianhydride or its corresponding tetraacid or diacid - diester in an A/B mole ratio ranging from about 2.0 to 1.05, preferably about 2.0 to 1.1, and mixtures thereof. The present invention is also directed to membranes of the above recited multi-block, polymeric material, especially membranes compising thin, dense films of said multi-block polymeric material deposited on a microporous support layer producing a thin film composite membrane. The membranes of the multi-block polymeric material, especially the thin film composite membranes, are useful for separating aromatic hydrocarbons from mixtures of same with non-aromatic hydrocarbons under perstraction or pervaporation conditions.

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