Mediators suitable for the electrochemical regeneration of NADH,

Details Mediators suitable for the electrochemical regeneration of NADH, Mediators suitable for the electrochemical regeneration of NADH,

1995-06-06

1996-05-28

Niebling, John

Chemistry: electrical and wave energy

Apparatus

Electrolytic

435817, 401 42, 401 43, C25B 1106, C25B 1112, C25B 1114

Patent

active

055207863

ABSTRACT:
Disclosed is an improved electrode suitable for the electrochemical regeneration of the co-enzymes NADH and NADPH. The electrode has imparted on its surface a mediator function which is a 3-phenylimino-3H-phenothiazine or a 3-phenylimino-3H-phenoxazine. Also disclosed is a method of improving the performance of a biochemical fuel cell which operates with a dehydrogenase as a catalyst and a co-enzyme as the energy-transferring redox couple which involves using the improved electrode in the fuel cell.

REFERENCES:
patent: 4490464 (1984-12-01), Gorton et al.
patent: 4710570 (1987-12-01), Thien
patent: 5373348 (1994-12-01), Inoue et al.
B. Persson, A Comparative Study of 3,7-Diaminopheonxazine . . . , J. Electroanal. Chem. 292 (1990) 115-138.
Doubova et al., Polyaniline a a Cathode for O.sub.2. . . , Electrochimica Acta, vol. 34, No. 3, pp. 337-343, 1989.

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