Meconium assay procedure

Chemistry: analytical and immunological testing – Including sample preparation – Liberation or purification of sample or separation of...

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436 92, 436 98, 436161, 436174, 436177, 436816, 436901, 73 6152, 73 6153, 73 6155, 210635, 210656, 210660, 2101982, G01N 118

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055873235

ABSTRACT:
A improved method for preparing a concentrated meconium extract containing basic and acid-neutral target analytes present in a meconium sample suspected of containing the target analytes is provided. The meconium sample is extracted with a mixed solvent of acetonitrile and a volatile organic acid and the resulting organic phase is separated. The organic phase is diluted with water to provide an organic solution which is passed through a mixed mode solid phase extraction column having strong cation exchange and hydrophobic functionality. Acid-neutral and basic target analytes are sequentially eluted from the column and the eluates are combined to form a combined extract. The combined extract is evaporated to dryness and reconstituted in buffer to provide a clean concentrated neonatal meconium extract for use in qualitative and quantitative analyses.

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patent: 5326708 (1994-07-01), Lewis
patent: 5532131 (1996-07-01), Lewis
Browne et al. Journal of Chromatography-Biomedical Applications, vol. 575, 1992, pp. 158-161.
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Lewis et al. Clinical Toxicology, vol. 32 (6), 1994, pp. 697-703.
Ostrea et al. The Journal of Pediatrics, vol. 122, No. 1, Jan. 1993, pp. 152-154.

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