Matrix metalloproteinase inhibitors

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Having -c- – wherein x is chalcogen – bonded directly to...

Reexamination Certificate

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Details

C548S472000, C562S430000, C562S450000

Reexamination Certificate

active

10559600

ABSTRACT:
Compounds of formula (I):wherein:Q represents an optionally substituted 5- or 6-membered aryl or heteroaryl ring;X represents O, S, NR5or CR6R7;Y represents CHOH, CHSH, NOR8, CNR8or CNOR8;Z represents a bond, CR10R11, O, S, SO, SO2, NR10, OCR10R11, CR10R11O or Z,R4and Q together form an optionally substituted fused tricyclic group;R1, R1′, R3and R3′each independently represents H, C1-6alkyl or C1-4alkylaryl;R2represents CO2R8, CONR5OR9or NR5COR9;R4represents optionally substituted 5- or 6-membered aryl or heteroaryl;R5represents H or C1-3alkyl;R6and R7each independently represents H, C1-3alkyl or halo;R8represents H or C1-2alkyl;R9represents H or C1-3alkyl;R10and R11each independently represents H, C1-6alkyl or C1-4alkylaryl; and physiologically functional derivatives thereof, processes for their preparation, pharmaceutical formulations containing them and their use as inhibitors of matrix metalloproteinase enzymes (MMPs) are described.

REFERENCES:
patent: 6350885 (2002-02-01), O'Brien et al.
patent: WO 98/09940 (1998-03-01), None
Barron, et al., J. Med. Chem., 1968, vol. 11, No. 6, pp. 1139-1144.
Robertson, L.W. et al., Chemical Abstract Service, May 12, 1984, “Microbiological Oxidation of the Pentyl Side Chain of Cannabinoids”, Abstract No. XP002302182.
N Miyaura et al., “Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds”, Chem. Rev., 1995, 95, 2457-2483.
A. Suzuki, “Recent Advances in the Cross-Coupling Reactions of Organoboron Derivatives with Organic Electrophiles, 1995-1998”, J. Oranometallic Chem., 1999, 576, 147-168.

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