Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...
Reexamination Certificate
1998-02-23
2001-07-03
Cain, Edward J. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Mixing of two or more solid polymers; mixing of solid...
C525S116000, C525S120000, C525S122000, C523S220000, C521S050000
Reexamination Certificate
active
06255391
ABSTRACT:
The present invention relates to a material for producing a building material or a shaped article, to building materials and shaped articles such as sheets made from such material, and to methods of producing building materials and shaped articles.
German Patent No. 21 59 735 published in 1976 describes the use of old vehicle tires, which are transformed by grinding to rubber powder (“rubber meal”) and/or coarse rubber powder. (“rough rubber meal”) to be used for the manufacture of Ion exchangers.
German Publication (“Auslegeschrift”) No. 1086437 describes a process of production of anion-selective membranes (diaphragms) whereby a mixed polymer containing 25 to 70% of an aromatic mono-vinyl-compound and of an aliphatic conjugated diene-compound is formed to a film-like membrane, this membrane being made insoluble by cyclisation or vulcanisation and which will then be chlorine-alcylated and finally animated.
In German Patent No. 21 59 735 it is stated that according to the process of German Publication No. 1 086 437 a defined compound namely a certain mixing polymer, consisting of aromatic and aliphatic parts, is the starting material, whereas according to German Patent No. 21 59 735 the rubber powder and/or the coarse rubber powder is a carbon (soot) filled vulcanisate.
In German Patent No. 21 59 735 it is further explained that a further difference from the prior art according to German Publication No. 1086473 is the fact that the latter describes the production of membranes whereas in the case of the products of Patent 21 59 735, there is no defined shape.
In relation of the definitions of the contents of rubber-powder (“rubber meal”) or coarse rubber powder (“rough rubber meal”) in the present specification, it is intended that the definitions will be the same as those used in German Patent No. 21 59 735.
The other prior art described in German Patent No. 21 59 735 is also included herein by reference.
Viewed from one aspect the invention provides a material for producing a building material or a shaped article, wherein said material comprises a melt-mixture of thermoplastic material and rubber material.
Viewed from another aspect the invention provides a mixture for melting to form a building material or a shaped article, said mixture comprising a thermoplastic material mixed with a rubber material.
The basis of this invention is the surprising realization that a mixture of rubber and thermoplastic materials are extremely apt to be shape-transformed to a building-material or a shaped article, for example by way of extrusion, especially by extrusion at higher temperatures in order to produce sheet-like products.
It is preferred to provide a mixture of rubber powder and/or rough rubber powder with thermoplastics which are powder-like or which consist of separated particles, possibly together with fillers suitable for these starting materials or with inlayed material like glass filaments and/or metal-filaments. Thus the mixture may eventually be provided with additional admixed fillers and/or inlayed material.
Preferably, the rubber material and the thermoplastic material in the shape of particular products or articles are bound together mechanically and/or by heat and/or by pressure and or by radiation.
Viewed from another aspect the invention provides a method of producing a building material or a shaped article, comprising mixing a thermoplastic material with a rubber material, heating said mixture to form a melt-mixture and forming said melt mixture to the required form of said building material or said shaped article.
A preferred method of manufacture consists in mechanically mixing the starting materials in granular form followed by using an extrusion-device in order to achieve the wanted shape, for example the shape of sheets.
Coarse rubber powder is especially preferred as the rubber starting material.
As starting material for the thermoplastic content, polyethylene in powder-form is especially suitable, whereby old polyethylene which is made by recycling for example of polyethylene bottle closures is preferably used.
The materials according to this invention can especially be made into sheets for roofing purposes and have excellent chemical and physical properties. These sheets are extremely weather (corrosion) and temperature resistant; for example measurements on test roofs using the sheeting of the invention showed that the sheeting could resist temperatures between minus 20 degrees Celsius and plus 80 degrees Celsius without any damage.
A further advantage of the sheets is their very low inflammability.
The sheets according to this invention and other shaped materials according to this invention further can be used in a generally known manner as floor elements or acoustic insulation elements.
The mixture according to this invention can also be supplied as a so called melt-mixture which can then be further processed into end products.
Additional fields of using the materials according to this invention are insulating sheets in any dimensions and/or roofing underlay sheets.
As thermoplastic component of the material mixture according to this invention are to be named, apart from polyethylene, polypropylene, thermoplastic polyurethanes and polyvinyl compounds.
The breaking strain of the sheets made out of the material according to this invention lies in the area of 190 to 200%.
The specific weight lies in the area between 1,2 and 1,3.
The hardness is preferably in the area between 90-100, namely Shore A-hardness.
If necessary the material according to this invention can contain additional materials (additives) and/or fillers, for example foam-materials as granules with closed cells and/or with open cells for example polystyrene-granules.
Furthermore, filaments can be incorporated for example glass-filaments and/or metal-filaments and/or carbon fibres.
As brighteners can be incorporated pigments, for example titanium-dioxide.
Furthermore, irradiation tests were carried out on the materials according to the invention, which revealed that these materials have for example also a high resistance to ultra-violet-rays.
The present invention will be further described by the following example
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Cain Edward J.
Kasper Horst M.
Netro-Products GmbH & Co. KG
Wyrozebski Kat
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