Material and process for precisely controlled polymeric...

Stock material or miscellaneous articles – Composite – Of silicon containing

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C526S081000, C526S087000, C526S091000, C526S109000, C526S118000, C526S201000

Reexamination Certificate

active

10887629

ABSTRACT:
This invention provides a chemically coated surface for the electrophoretic separation application. The surface comprises of block copolymers prepared from addition monomers selected from a group consisting of acrylates and its derivatives, metharylates and its derivatives, styrene and its derivatives, acrylamide, methacrylamide, dimethacrylamide, N-monosubstituted acrylamide, N-monosubstituted methacrylamide, N,N-bissubstituted acrylamide, N,N-bissubstituted methacrylamide, vinyl acetate, vinyl pyrolidone, vinyl ether, acrylic acid and methacrylic acid. This invention also provides a chemical process for making the chemically coated surface for the electrophoretic separation application. The process comprises:(a) contacting the support surface with a coupling agent solution, then(b) contacting the support surface with a first living radical polymerizing solution, and optionally(c) contacting the support surface with a second living radical polymerizing solution.

REFERENCES:
patent: 5789487 (1998-08-01), Matyjaszewski et al.
patent: 5792331 (1998-08-01), Srinivasan
patent: 5807937 (1998-09-01), Matyjaszewski et al.
patent: 6372353 (2002-04-01), Karger
patent: 6653415 (2003-11-01), Bottcher et al.
patent: 2002/0103352 (2002-08-01), Sudor
patent: 2004/0176534 (2004-09-01), Rogers et al.
patent: 2004018556 (2004-01-01), None
English translation of JP 2004018556A.
Liu, Yong, et al, Polymer grafing via ATRP initiated from macroinitiato synthesized on surface, Langmuir, 2004, 20, 6710-6718.
Kong, Xiangxing, et al, Amphiphilic polymer brushes grown from the silicon surface by atom transfer radical polymerization, Macromolecules, 2001, 34, 1837-1844.
M. Husseman et al, Macromolecules, 1999, 32, 1424.
Strege, “Capillary Electrophoretic Protein Separations in Polyacrylamide-Coated Silica Capillaries and Buffers Containing Ionic Surfactants” Journal of Chromatography, 1993, 337-344, 630. Eksevier Science Publishers, Amsterdam.
Wan, “Bonded Dimethylacrylanides as a Permanent Coating for Capillary Electrophoresis” Journal of Chromatography, 2001, 59-70, 924, Elsevier Science Publishers. Amsterdam.
Cobb, “Electrophoretic Separations of Proteins in Capillaries With Hydrolytically Stable Surface Structures” Anal. Chem. 1990, 2478-2483 62. American Chemical Society.
Hjerten “High Performance Electrophoresis, Elimination of Eletroendosmosis and Solute Adsorption” Journal of Chromatography, 1985, 191-198, 347, Elsevier Science Publishers, Amsterdam.
Chiari “Synthesis and Characterization of Capillary Columns Coated With Glycoside—Bearing Polymer” Anal. Chem. 1996. 2731-2736. 68 American Chemical Society.
Dolink “DNA Sequencing by Capillary Electrophoresis” J. Biochem. Biophys. Methods 1999, 103-119, 41. Elsevier Science Publishers. Amsterdam.
Huang “Surface-Confined Living Radical Polymerization for Coating in Capillary Electrophoresis.” Anal. Chem. 1998, 4023-4029. 70. American Chemical Society.
Deqing Xiao and Mary J. Wirth “Kinetics of Surface-Initiated Atom Transfer Radical Polymerization of Acrylamide on Silica” Macromolecules 2002, 35, 2919-2925.
Mircea Tesdorescu and Krzysztof Matyjaszewski ATOM Transfer Radical Polymerization of (Meth)acrylamides Macromolecules 1999, 32, 4826-4831.
X. Huang and M. J. Wirth “Surface Initiation of Living Radical Polymerization for Growth of Tethered Chains of Low Polydispersity” Macromolecules 1999, 32, 1694-1696.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Material and process for precisely controlled polymeric... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Material and process for precisely controlled polymeric..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Material and process for precisely controlled polymeric... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3889572

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.