Material and process for controlled thin polymeric coatings...

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Reexamination Certificate

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C526S081000, C526S087000, C526S091000, C526S109000, C526S118000, C526S201000

Reexamination Certificate

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10887672

ABSTRACT:
This invention provides a chemically coated surface for the plastics surface such as contact lens. The chemical surface coating comprises of at least one addition polymer prepared from addition monomers selected from a group consisting of acrylates and its derivatives, metharylates and its derivatives, styrene and its derivatives, acrylamide, methacrylamide, dimethacrylamide, N-monosubstituted acrylamide, N-monosubstituted methacrylamide, N,N-bissubstituted acrylamide, N,N-bissubstituted methacrylamide, vinyl acetate, vinyl pyrolidone, vinyl ether, acrylic acid and methacrylic acid. This invention also provides a chemical process for making the chemically coated surface on the plastics surface. The process comprises:(a) contacting the plastics surface with a coupling agent solution, then(b) contacting the plastics surface with a first living radical polymerizing solution, and optionally(c) contacting the plastics surface with a second living radical polymerizing solution.

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Xianyi Chen, Steven Armes, Surface Polymerization of Hydrophilic Methacrylates from Ultrafine Silica SOIs in Protic Media at Ambient Temperature: A Novel Approach to Surface Functionalization Using a Polylcetrolyic Macroinitiator, 2003, Adv. Mater, 15(18), 1558-1562.
English Translation of JP 2004-018556A.
M. Husseman et al, Macromolecules, 1999, 32, 1424.
Huang “Surface-Confined Living Radical Polymerization for Coating in Capillary Eletrophorsis.” Anal. Chem. 1998, 4023-4029, 70. American Chemical Society.
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