Manufacturing polyacrylate esters with long-chain hydrocarbon an

Compositions – Preservative agents – Anti-corrosion

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44301, 252309, 252DIG1, 5253306, 5263297, B01F 1742, C08F 814, C08F 2018, C08F12018

Patent

active

051338980

ABSTRACT:
Polyacrylate esters with long-chain hydrocarbon and polyoxyalkylene groups are disclosed, which are prepared by transesterification of polyacrylate alkyl esters, the alkyl groups of which have 1 to 4 carbon atoms and which were obtained by free radical polymerization, wherein the transesterification is carried out with a mixture of selected alcohols and polyoxyalkylene monools. Compared to products obtained by copolymerization, the transesterification products are largely free of undesirable low molecular weight components, have a narrow molecular weight distribution and exhibit excellent surfactant properties. They are useful especially as W/O emulsifiers for natural and synthetic oils.

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