Manufacturing of high molecular weight polyester

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528275, 528276, 528277, 528485, 528486, 528489, C08G 6326

Patent

active

046544135

ABSTRACT:
A polybutylene terephthalate is manufactured by the steps of polycondensating in the liquid phase terephthalic acid or a lower alcohol ester thereof as the acid component and 1,4-butanediol as the diol component to obtain a prepolymer of polybutylene terephthalate, solidifying the prepolymer and further polymerizing the prepolymer in the solid phase to obtain a polybutylene terephthalate of a higher polymerization degree, 0.001 to 5 percent by weight, based on the prepolymer, of a nucleator being added to the polymerization mixture at any time during a period of from the monomer-mixing stage before the starting of the solid phase polymerization, the solid phase polymerization being conducted in the presence of the nucleator uniformly dispersed in the polymerization mixture. The solid polymerization can be treated subsequently to the liquid polymerization and can proceed in a short time.

REFERENCES:
patent: 4043971 (1977-08-01), Wurmb et al.
patent: 4163002 (1979-07-01), Pohl et al.
patent: 4351758 (1982-09-01), Lu
patent: 4391938 (1983-07-01), Memon et al.
patent: 4460731 (1984-07-01), Kochanowski et al.
patent: 4532319 (1985-07-01), Wendling
patent: 4536531 (1985-08-01), Ogawa et al.

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