Manufacturing method for differential denier and...

Plastic and nonmetallic article shaping or treating: processes – With twining – plying – braiding – or textile fabric formation

Reexamination Certificate

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C264S172120

Reexamination Certificate

active

06787081

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a manufacturing method for differential denier and differential cross section fiber and fabric.
DESCRIPTION OF THE PRIOR ART
For a long time, synthetic fiber serves as garments. As the demand to the tactility and mechanical property of synthetic fibers requested by the consumer are increasing, the fiber industry has been actively engaging in the study, trying to develop a fiber fabric having differential denier and differential cross section and featuring in the similar character with the tactility and luster of natural silk fiber to satisfy the consumer's needs. For this purpose, several patents have been disclosed recently, such as JP-A-6-41868/1994, JP-A-6-287835/1994, JP-A-9-59826/1997 and Chinese Patent Application Publication CN1208780A published on Feb. 24, 1999 etc., wherein two polymers with different alkali dissolution rate are melted respectively, after being blended in an adjusted ratio, a static mixing element or a static mixer is introduced to obtain a full blending, then after spinning a fiber with differential denier and differential cross section is formed. When produced in this method, a static mixer is mounted into the pack assembly. However, in order to save space of equipment, the size of pack assembly is not too large; so the size of static mixer is needed generally to reduce to a limited size to be amounted into the pack assembly. In addition, in order to obtain a better blending effect, the number of element in the static mixer is needed to be a specific number in general. But when the size of static mixer is reduced and the number of mixing element is increased, some problems appear, such as: static mixer is expensive; when the polymer passes through the static mixer, due to the high pressure drop, it imposes an adverse effect on the life-span of the pack assembly; due to the heat splitting released by the polymer, the fiber strength is decreased and breakage of the yarn tends to occur more frequently, therefore influencing the product quality.
Methods to the Problems
In order to solve above problems, the present inventor develops the following method after constant study, which comprising melting two polymers with different alkali dissolution rate respectively, blending the two polymers in an adjusted ratio, then spinning the blend from a pack assembly consisting of distributor for producing general split type microfiber and spinnerette with spinning orifice of different shape to produce fiber, which is directly formed into SDY (spin draw yarn) subjecting to a direct spin-draw process, or formed into a flat yarn and draw texture yarn subjecting to draw twisting process and false twisting process or formed into a composite flat yarn and composite draw texture yarn subjecting to composite draw twisting process and composite false twisting process; spinning said SDY, flat yarn, draw texture yarn, composite flat yarn or composite draw texture yarn to fabric and subjecting the fabric to alkali treatment to obtain fabric with differential denier and differential cross section fabric in excellent tactility and luster.
The method is described in particular as follows:
Two polymers with different alkali dissolution rate, such as polyester polymers, are prepared, wherein a modified polyester polymer with a quicker alkali dissolution rate is prepared by adding a third component such as diethylene glycol, propylene glycol, cyclohexamethylene glycol, polyethylene glycol, terephthalic acid, isophthalic acid, sulfo isophthalic acid, adipic acid, azelaic acid and sebacic acid into the polyester polymer and subjecting to polymerization; and a general polyester polymer unmodified is used as a polyester polymer with a slower alkali dissolution rate. Both of the polymers with different alkali dissolution rate are added to the NaOH solution at a temperature of 105° C. and at a concentration of 1.0 wt %, the bath ratio of the polymers to the alkali solution is adjusted to 1:45, after 10 minutes, the ratio of the polymer with a quicker dissolution rate to the polymer with a slower dissolution rate in the alkali solution reaches to 275:1.
The two polymers with different alkali dissolution rate is melted respectively, then blended in an adjusted ratio; the blending ratio of polymer with a quicker dissolution rate to the polymer with a slower dissolution rate is in the range of 85:15 to 50:50, generally, the ratio of polymer with a quicker dissolution rate should not be too small; if the ratio is less than 15%, the fabric produced shall not obtain the delicate tactility after alkali treatment; if the ratio of polymer with a quicker dissolution rate exceeds 50%, after alkali treatment, the fabric has a monofilament which is too thin to obtain the proper effect of differential denier and differential cross section, and too large proportion of alkali treatment shall raise the manufacturing cost and induce insufficient tear strength of the fabric, so the most proper ratio of polymer with a quicker dissolution rate to the polymer with a slower dissolution rate is in the range of 85:15 to 50:50.
Metering pump is used to adjust the blending ratio of two melted polymers with different alkali dissolution rate to the range of 85:15 to 50:50, and the two polymers are fed into the pack assembly illustrated in
FIG. 1
, wherein
1
is a polymer with a slower alkali dissolution rate;
2
is a polymer with a quicker alkali dissolution rate;
3
is filter sand;
4
is filter screen;
5
is a distributor for producing general split type microfiber;
6
is a spinnetrtte with spinning orifice of different shape. The two melted polymers, polymer
1
and polymer
2
, with different alkali dissolution rate are fed into the pack assembly by a metering pump, after that, they pass through the filter sand
3
and filter screen
4
to remove the impurity in the polymers, then pass through the distributor for producing general split type microfiber
5
, where the two polymers are split and arranged, finally the polymers pass through the spinnetrtte with spinning orifice of different shape
6
to produce fibers with differential cross section exhibiting irregular arrangement.
The strand of filament spun from the spinnetrtte with spinning orifice of different shape, can be cooled, oiled and wound to obtain POY (partially oriented yarn) or MOY (middle oriented yarn), or can be cooled, oiled, directly spun-drawn and wound to obtain SDY (spin draw yarn). The POY and MOY can be produced into flat yarn and draw texture yarn subjecting to the draw twisting process and false twisting process, or they can combine with other type of yarn to produce composite flat yarn or composite draw texture yarn subjecting to the draw twisting process and false twisting process. Subjecting the fabric produced by above described flat yarn, draw texture yarn, composite flat yarn, composite draw texture yarn or SDY (spin draw yarn) to alkali treatment can obtain fabric with differential denier and differential cross section in excellent tactility and luster.
FIG. 2
is an illustrative view of the split design used by the distributor for producing general split type microfiber according to the invention, wherein
7
is in 12 splits;
8
is in 16 splits;
9
is in 24 splits, the more splits the distributor has, the more significant blending effect will be obtained by the two polymers passing through the spinnerette with spinning orifice of different shape, but the distributor is extremely expensive. The present invention just illustrates 3 types of split design in
FIG. 2
, but the 3 types of split design should not be considered as a limitation to the present invention.
FIG. 3
is an illustrative view of the shape design of the spinnerette with spinning orifice of different shape according to the invention, wherein
10
is a “+” shaped spinning orifice;
11
is an octagon shaped spinning orifice;
12
is a Y-shaped spinning orifice. Spinnerette with spinning orifice of different shape refers to the designed spinnerette with non-round spinning orifice, if a spinnerett

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