Manufacture of tertiary and secondary alcohols by the action of

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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260410, 558451, 560179, 560266, 568813, C07C 2914, C07C 29143, C07C 29136

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050915983

ABSTRACT:
Process of preparation of alcohols by the reaction of an organic halide with a carbonyl compound in an organic solvent, in the presence of metallic manganese, followed by hydrolysis of the reaction product; the reaction is initiated and activated by an ester present in the reaction medium.

REFERENCES:
patent: 2414012 (1947-01-01), Boord
patent: 2838576 (1958-06-01), Normant
patent: 3308172 (1967-03-01), Rudner et al.
patent: 3423446 (1969-01-01), Kobetz et al.
"Les Organomanganeux: utilisations en synthese organique" by G. Cahiez, L'Actualite Chimique, Sep. 1984, p. 27.
"Carbon-Carbon Bond Formation with Metallic Manganese" by T. Hiyama et al., Chemistry Letters, pp. 1237-1238, 1983.

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