Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1988-12-28
1992-02-25
Brust, Joseph Paul
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
260410, 558451, 560179, 560266, 568813, C07C 2914, C07C 29143, C07C 29136
Patent
active
050915983
ABSTRACT:
Process of preparation of alcohols by the reaction of an organic halide with a carbonyl compound in an organic solvent, in the presence of metallic manganese, followed by hydrolysis of the reaction product; the reaction is initiated and activated by an ester present in the reaction medium.
REFERENCES:
patent: 2414012 (1947-01-01), Boord
patent: 2838576 (1958-06-01), Normant
patent: 3308172 (1967-03-01), Rudner et al.
patent: 3423446 (1969-01-01), Kobetz et al.
"Les Organomanganeux: utilisations en synthese organique" by G. Cahiez, L'Actualite Chimique, Sep. 1984, p. 27.
"Carbon-Carbon Bond Formation with Metallic Manganese" by T. Hiyama et al., Chemistry Letters, pp. 1237-1238, 1983.
Cahiez Gerard
Chavant Pierre-Yves
Tozzolino Pierre
Brust Joseph Paul
Societe Nationale Elf Aquitaine
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