Manufacture of tertiary and secondary alcohols by the action of

Details Manufacture of tertiary and secondary alcohols by the action of Manufacture of tertiary and secondary alcohols by the action of

1990-08-28

1992-02-25

Brust, Joseph Paul

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

549497, 260410, 558451, 560179, 568598, 568807, 568825, 568828, C07C 2914, C07C 29143, C07C 29136

Patent

active

050915975

ABSTRACT:
Process of preparation of secondary or tertiary alcohols by the action of an organic halide on metallic manganese, in the presence of a carbonyl compound in a solvent followed by hydrolysis; a compound of a metal of Groups II to VIII of the Periodic Classification of the Elements, less electropositive than manganese, is present in the reaction medium.

REFERENCES:
patent: 3579575 (1971-05-01), Bouniot
patent: 3631179 (1971-12-01), Urry
patent: 3706809 (1972-12-01), Moroe et al.
"Les Organomanganeux: ultilisation en Synthese Organique" by G. Cahiez, L'Actualite Chimiqux, Sep. 1984, p. 27.
"Carbon-Carbon Bond Formations with Metallic Manganese" by T. Hiyama, et al., Chemistry Letters, pp. 1237-1238.

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