Manufacture of fluorinated alcohols

Organic compounds -- part of the class 532-570 series – Organic compounds – Boron containing

Reexamination Certificate

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C568S001000

Reexamination Certificate

active

06992224

ABSTRACT:
Present invention relates to a process for the manufacture of fluorinated alcohols as well as borates which are employed in the manufacture of the fluorinated alcohols. Fluorinated alcohols of the formulae HOCHRCF(CF3)CHFCF(CF3)2and HOCHRCF(CF(CF3)2)CHFCF3, HOCHRCF(CF2CF3)CH(CF3)2and HOCHRC(CF3)2CHFCF2CF3are made by heating a mixture of a borate of the formula (RCH2O)3B, wherein R═H or a C1to C7alkyl group, with perfluoro-4-methyl-2-pentene or perfluoro-2-methyl-2-pentene and a free-radical initiator to form a mixture of borates, optionally separating the mixture of borates from any reactants, solvents, and by-products; hydrolyzing the mixture of borates to form a hydrolysis product mixture; and separating the alcohols from the hydrolysis product mixture.

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