manufacture of certain cyclic ester oligomers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

Reexamination Certificate

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C528S308600, C528S491000, C528S493000, C528S497000, C528S501000, C526S067000, C526S068000, C526S069000, C526S070000, C526S206000, C526S208000, C524S732000, C524S768000, C524S770000

Reexamination Certificate

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06979720

ABSTRACT:
Enzymes which are capable of catalyzing esterifications and/or transesterifications such as selected lipases and esterases can, under specified conditions, convert certain lower linear oligomers of polyesters to their cyclic ester oligomers in quantities greater than would be predicted by thermodynamic calculation or prior art methods. The cyclic ester oligomers are useful for the production of higher molecular weight linear polyesters.

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patent: 5661214 (1997-08-01), Brunelle et al.
Berkane, Christopher et al., “Lipase-Catalyzed Polyester Synthesis in Organic Medium. Study of Ring-Chain Equilibrium”, Macromolecules, 1997, 30, p7729-7734.
Mezoul, Gilles et al., “Enzyme-catalyzed syntheses of poly(1,6-hexanediyl isophthalate) and poly(1,6-hexanediyl terephthalate) in organic medium”, Polymer Bulletins, 36, 541-548 (1996).
Lavalette, Arnuad et al., “Lipase-Catalyzed Synthesis of a Pure Macrocyclic Polyester from Dimethyl Terephthalate and Diethylene Glycol”, BioMacromolecules, vol. 3, No. 2, Mar./Apr. 2002.
Biomacromolecules, Mar./Arpil 2002, Lipase-Catalyzed Synthesis of a Pure Macrocyclic Polyester form Dimethyl Terephthalate and Diethylene Glycol, Arnaud Lavalette et al.
Intramolecular Reaction in Polycondensations. I. The Theory of Linear Systems, Journal of chemical Physics, vol. 18, No. 12, Dec. 1950, Homer Jacobson et al.
Macormolecules 1997, 30-7729-7734, Lipase-Catalyzed Polyester Synthesis in Organic Medium, Study of Ring-Chain Equilibrium, Berkane et al.
2445 Polymer Bulletin 36(1966) May., No. 5, Berlin, DE., Enzyme-Catalyzed Synthesis of Poly(1,6-hexanediylisophthalate) and poly(1,6-hexanediyl terephthalate in organic medium, Gilles Mezoul.

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