Manufacture of carbamates from cyanogen

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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2604537, 560132, 560133, 560134, 560157, 560162, 560166, C07C12504, C07C11918, C07C11920, C07C 6800

Patent

active

043010873

ABSTRACT:
Carbamates, such as ethyl carbamate, are prepared by contacting an alcohol, such as ethanol, with cyanogen and water in the presence of a dipolar, aprotic solvent, such as acetonitrile, and an acid catalyst, such as hydrochloric acid.

REFERENCES:
patent: 2819292 (1958-01-01), Welcher
patent: 3170947 (1965-02-01), Gruber
patent: 3301883 (1967-01-01), Gruber
Fahnenstich, Chemiker-Zertung, 96 pp. 388-396 (1972).

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