Manufacture of calcium hypochlorite

Chemistry of inorganic compounds – Halogen or compound thereof – Ternary compound

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C01B 1106

Patent

active

043978320

ABSTRACT:
A process for making calcium hypochlorite from caustic soda calcium hydroxide and chlorine by feeding to a stirred reactor an aqueous solution of the total required amount of caustic soda and an aqueous suspension of up to 80% by weight of the total required amount of calcium hydroxide, passing chlorine through the mixture until a redox potential of 650 to 800 mV is reached and while continuing chlorination adding the remaining of the calcium hydroxide at such rate with respect to chlorine that redox potential gradually increases to between 850 and 950 mV. This process prevents thickening and caking which are a recognized problem with conventional batch processes.

REFERENCES:
patent: 934467 (1909-09-01), Schultze
patent: 1583421 (1926-05-01), Pistor
patent: 1884200 (1932-10-01), Philipp
patent: 2889199 (1959-06-01), Osborne
patent: 3760064 (1973-09-01), Droste
patent: 3956471 (1976-05-01), Pullman
patent: 4364917 (1982-12-01), Tiedemann

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