Manufacture of block polyester polyols, and polyurethanes derive

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From reactant having at least one -n=c=x group as well as...

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528 81, 528 82, 528291, C08G 1842

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active

047897198

ABSTRACT:
A method for the manufacture of polyester polyols is disclosed. The method comprises feeding to a reactor at least one aliphatic carboxylic acid or ester thereof, at least one secondary dihydric alcohol and at least one primary trihydric alcohol, heating the resultant admixture and removing water. When at least 95% of the water has been removed, N-phenyl dialkanolamine and additional primary trihydric alcohol are added and heating is continued. The reactants are selected so that the range of molecular weights thereof is not more than 100. A block polyester polyol is obtained. Polyurethanes obtained from the polyester polyol tend to have more uniform and superior properties. The polyurethanes may be used in variety of end uses.

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patent: 4400477 (1983-08-01), Blanpied
patent: 4525574 (1985-06-01), Altounian
patent: 4608413 (1986-08-01), Nachtkamp
patent: 4716213 (1987-12-01), Altounian et al.

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