Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1982-11-15
1984-08-14
Harris-Smith, Y.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260406, 2604105, 560131, C11C 302
Patent
active
044656335
ABSTRACT:
A process is described for the manufacture of aryl esters such as phenyl esters by liquid phase reaction of an aromatic compound such as benzene with molecular oxygen in the presence of a carboxylic acid preferably having 6 or more carbon atoms over a catalyst composed essentially of a compound of palladium, a compound of antimony and a compound of at least one member selected from the group consisting of chromium, cobalt, nickel, manganese, iron, and tin wherein the aromatic compound is added continuously to the reaction and water formed in the reaction is rapidly and continuously removed from the reaction zone.
REFERENCES:
patent: 3493605 (1970-02-01), Selwitz
patent: 3646111 (1972-02-01), Hornig et al.
patent: 3651127 (1972-03-01), Hornig et al.
patent: 3772383 (1973-11-01), Kominami et al.
patent: 4229587 (1980-10-01), Murib
Goel Anil B.
Throckmorton Peter E.
Ashland Oil Inc.
Harris-Smith Y.
Jones John F.
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