Manufacture of alkanols from synthesis gas

Details Manufacture of alkanols from synthesis gas Manufacture of alkanols from synthesis gas

1981-06-26

1982-06-01

Mars, Howard T.

Chemistry: fischer-tropsch processes; or purification or recover

Liquid phase fischer-tropsch reaction

252428, 252430, 252471, 252472, C07C 2706

Patent

active

043329144

ABSTRACT:
This invention concerns a process of making alkanols and particularly methanol which comprises the steps of contacting a mixture of CO and H.sub.2 with a catalyst system comprising a ruthenium-containing compound and a halogen-free rhenium-containing compound or a halogen-free manganese-containing compound dispersed in a low melting quaternary phosphonium base or salt, and heating said resultant reaction mixture under a pressure of 500 psig or greater at a temperature of at least 150.degree. C.

REFERENCES:
patent: 4206134 (1980-06-01), Kugler et al.
patent: 4265828 (1981-05-01), Knifton

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