Manufacture of aliphatic hydroxycarbonyl compounds etherified wi

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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252476, 568414, 568471, 568496, C07C 4538

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active

042332460

ABSTRACT:
Aliphatic hydroxycarbonyl compounds etherified with aliphatic groups are prepared by oxidizing hydroxyalcohols in the presence of a metal catalyst which consists of one or more layers, each of a particular weight and each containing particles of a particular size, the catalyst bed also having a particular total thickness, and the catalyst components used being silver and copper, with or without added copper/tin/phosphorus or silver alone. The etherified hydroxyaldehydes and hydroxyketones obtainable by the process of the invention are valuable starting materials for the preparation of dyes, pesticides, plastics and scents.

REFERENCES:
patent: 2170855 (1939-08-01), Chitwood
patent: 3106581 (1963-10-01), Neely
patent: 3941811 (1976-03-01), Vignau
patent: 3948997 (1976-04-01), Howe et al.
patent: 3956184 (1976-05-01), Abramovich et al.

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