Manufacture of 4,4'-diisopropylbiphenyl

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By condensation of entire molecules or entire hydrocarbyl...

Patent

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

585466, C07C 268

Patent

active

050269402

ABSTRACT:
The selective isopropylation of biphenyl or 4-isopropylbiphenyl to diisopropylbiphenyl while maximizing the yield of the 4,4'-diisopropoylbiphenyl isomer is achieved by carrying out the reaction in the presence of an acidic crystalline molecular sieve with pore aperture 5.7-6.1 .ANG., preferably SAPO-11 or ZSM-12.

REFERENCES:
patent: 3251897 (1966-05-01), Wise
patent: 4026959 (1977-05-01), Kemme et al.
patent: 4064068 (1977-12-01), Haseltime, Jr.
patent: 4179472 (1979-12-01), Cobb
patent: 4415544 (1983-11-01), Kokotailo et al.
patent: 4469908 (1984-09-01), Burress
patent: 4480142 (1984-10-01), Cobb
patent: 4567029 (1986-01-01), Wilson et al.
patent: 4795847 (1989-01-01), Weitkamp et al.
D. B. Priddy, "Alkylation of Biphenyl Under Mild Friedel Crafts Conditions", I & EC Product Research and Development, vol. 8, No. 3, Sep. 1969.
K. Hyska, Chem. Prun., 1971.
E. G. Derouane, "Diffusion and Shape-Selective Catalysts in Zeolites", Intercalation Chemistry, Ed. by M. Stanley Whittingham (Academic Press, 1982).
J. M. Bennett et al., Zeolites 7, (1987) and P. A. Jacobs, et al., "Synthesis of High Silica Alumino-Silicate Zeolites", Studies in Surface Science and Catalysis, No. 33, Elsevier, 1987.
Meier, W. M. and Olson, D. H., "Atlas of Zeolite Structure Types", 2nd Ed., Structure Commission of the International Zeolite Association, Butterworhts, 1987.
Lee, et al., Catalyst Letters 2, (1989).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Manufacture of 4,4'-diisopropylbiphenyl does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Manufacture of 4,4'-diisopropylbiphenyl, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Manufacture of 4,4'-diisopropylbiphenyl will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-1041835

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.