Manufacture of 1,3-propanediol esters from formaldehyde and ethy

Details Manufacture of 1,3-propanediol esters from formaldehyde and ethy Manufacture of 1,3-propanediol esters from formaldehyde and ethy

1998-12-02

2000-08-29

Geist, Gary

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

C07C 6700

Patent

active

06111135&

ABSTRACT:
Disclosed is a process for manufacturing an ester of 1,3-propanediol, comprising, contacting at a temperature of about 0.degree. C. to about 250.degree. C., ethylene, formaldehyde or a form of formaldehyde, a carboxylic acid, and a compound of the formula MZ.sub.n.Q.sub.t, wherein:

REFERENCES:
patent: 4322355 (1982-03-01), Horvitz et al.
B.B. Snyder in B. Trost et al., Ed., Comprehensive Organic Synthesis, 2, Pergamon Press, Oxford, 527-534, 1991.
D.R. Adams, et al., Synthesis, 661-672, 1977.

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