Manufacture of 1, 1-difluoroethane

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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570166, C07C 1708

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active

058667296

ABSTRACT:
A process for the selective and high yield preparation of 1,1-difluoroethane (CHF.sub.2 --CH.sub.3, HFC-152a) from chloroethene and anhydrous hydrogen fluoride is disclosed. The process involves the reaction of chloroethene with anhydrous hydrogen fluoride in a liquid phase between the temperatures of 30.degree. and 160.degree. C. in the presence of a tin catalyst and at least one compound selected from the group consisting of alkali metal halides and saturated halogenated hydrocarbons.

REFERENCES:
patent: 2495407 (1950-01-01), Chapman et al.
patent: 3862995 (1975-01-01), Martens et al.

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