Mannich base polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528137, 528149, 528162, 528230, 528266, 508558, C08G 1402

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active

056080298

ABSTRACT:
A process for producing an oil soluble interpolymer polymer of 1,2-alkylenediamine such as N-ethyl ethylenediamine, aldehyde-provider such as formaldehyde, and ortho-unsubstituted hydroxyaromatics such as 4-polyalkylene phenol is disclosed. The decyclized Mannich Base monomer units provide a higher viscosity material which is suitably substituted with a long chain hydrocarbyl para substituent such as polyisobutylene or ethylene/alpha-olefin polymer. Various ortho-substituted hydroxyaromatics such as o-cresol may be used to control the degree of polymerization. The polymers are useful as dispersants or other lubricant additives.

REFERENCES:
patent: 4810354 (1989-03-01), Roling et al.
patent: 4857217 (1989-08-01), Gutierrez et al.
Chemical Abstracts, vol. 120, No. 20, May 16, 1994, abstract No. 249113m Radchenko et al. "Oil for Hydraulic Systems of Industrial Machinery", p. 237.
"Preparation of Amphiphilic Polyisobutylenes-b-polyethylenamines by Mannich Reaction. III. Synthesis of Polyisobutylenes-b-polyethylenamines", Journal of Polymer Science, Part A, 31, pp. 1959-1966 (1993).
"Preparation of Amphiphilic Polyisobutylenes-b-polyethylenamines by Mannich Reaction. I. Synthesis and Characterization of .alpha.-Phenololigoisobutylenes", Journal of Polymer Science, Part A, 31, pp. 1923-1939 (1993).
"Preparation of Amphiphilic Polyisobutylenes-b-polyethylenamines by Mannich Reaction II. Study of Mannich Reaction on Model Systems", Journal of Polymer Science, Part A, 31, pp. 1941-1958 (1993).

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