Manganese oxide composite electrodes for lithium batteries

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

Reexamination Certificate

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C429S218100, C429S223000, C429S224000, C429S231500, C429S231600, C429S128000

Reexamination Certificate

active

08080340

ABSTRACT:
An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula x{zLi2MnO3•(1-z)LiM′O2}.(1-x)LiMn2−yMyO4for 0<x<1; 0≦y≦0.5; and 0<z<1, comprised of layered zLi2MnO3.(1-z)LiM′O2and spinel LiMn2−yMyO4components, physically mixed or blended with one another or separated from one another in a compartmentalized electrode, in which M is one or more metal ions, and in which M′ is selected from one or more first-row transition metal ions, The electrode is activated by removing lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

REFERENCES:
patent: 4507371 (1985-03-01), Thackeray et al.
patent: 5240794 (1993-08-01), Thackeray et al.
patent: 5316877 (1994-05-01), Thackeray et al.
patent: 6660432 (2003-12-01), Paulsen et al.
patent: 6677082 (2004-01-01), Thackeray et al.
patent: 6680143 (2004-01-01), Thackeray et al.
patent: 6964828 (2005-11-01), Lu et al.
patent: 7303840 (2007-12-01), Thackeray et al.
patent: 7635536 (2009-12-01), Johnson et al.
patent: 7790308 (2010-09-01), Johnson et al.
patent: 2003/0108793 (2003-06-01), Dahn et al.
patent: 2003/0118904 (2003-06-01), Hosokawa et al.
M.H. Rossouw et al., Lithium Manganese Oxides From . . . Lithium Battery Applications, Mat. Res. Bull., vol. 26, (1991) pp. 463-473.
James C. Hunter, Preparation of a New Crystal Form of Manganese Dioxide, Journal of Solid State Chemistry 39, (1981), 142-147.
M. H. Rossouw et al. Structural Aspects of Lithium-Manganese-Oxide Electrodes for Rechargeable Lithium Batteries, Mat. Res. Bull., vol. 25 (1990), 173-182.
A. deKock et al., Defect Spinets in the System . . . and Electrochemical Characterization of Li2Mn4O9, Mat. Res. Bull. vol. 25, (1990), pp. 657-664.
M. Thackeray et al., The Versatility of MnO2 for Lithium Battery Applications, Journal of Power Sources, 43-44 (1993) 289-300.
M. Thackeray, Manganese Oxides for Lithium Batteries, Progress in Solid State Chemistry, 25 (1997) 1-71.
P. Kalyani et al., Lithium Metal Rechargeable Cells Using Li2MnO3 as the Positive Elecrode, Journal of Power Sources 80 (1990) 103-106.
K. Numata et al., Preparation and Electrochemical Properties of Layered Lithium-Cobalt-Manganese Oxides, Solid State Ionics 118 (1999) 117-120.
C.S. Johnson, Layered . . . Electrodes for Lithium Batteries, Electrochemical Society Inc., Proceedings, vol. 2000-36, (2001), pp. 47-60.
M. Balasubramanian et al., In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material, Journal of The Electro. Soc. 149 (2) (20002), A176-A184.
B. Ammundsen et al., Local Structure and First Cycle Redox . . . Cathode Material, Journal of the Electrochemical Society, 149 (2002), A431-A436.
Z. Lu et al., Synthesis, Structure, and Electrochemical Behavior of Li . . . , Journal of the Electrochemical Society, 149 (2002), A778-A791.
A. D. Robertson et al., The Origin of Electrochemical Activity in Li2MnO3, Chem. Commun. (2002) 2790-2791.
J. S. Kim et al., Layered xLiMO2 . . . Electrodes for Lithium Batteries, Electrochemistry Communications 4 (2002), 205-209.
A. R. Armstrong et al., Electrochemistry Beyond . . . Electrochemical and Solid-State Letters 7 (2004) A1-A4.
J.S. Kim et al., Electrochemical and Structural Properties of . . . Electrodes for Lithium Batteries, Chem. Mater. 16, (2004), 1996-2006.
C.S. Johnson et al., The Significance of the . . . Component in ‘Composite’ . . . Electrodes, Electrochemistry Communications 6 (2004), 1085-1091.
J.S. Kim et al., Preconditioned Layered Electrodes for Lithium Batteries, Journal of Power Sources, Jun. 2004.
M.N. Richard et al., The Effect of Ammonia Reduction on the Spinel Electrode Materials, . . . Solid State Ionics 73 (1994), 81-91.
Y. Shin et al., Origin of the Capacity of Spinel . . . In the 5 V Region, Electrochemical and Solid State Letters, 6 (2003), A249-A251.
Z. Lu et al., Understanding the Anomalous Capacity of . . . In Situ X-Ray Diffraction and Electrochemical Studies, Journal of The Electrochemical Society 149 (2002), A815-A822.
Y. Shao-Horn et al., Structural Characterization of Layered . . . Diffraction and Lattice Imaging, Journal of The Electrochemical Society, 146 (1999), 2404-2412.
P. G. Bruce, New Intercalation Compounds for Lithium Batteries, J. Mater. Chem. vol. 9, (1999), 193-198.
T. E. Quine et al., Layered LixMn1-yNiyO2 Intercalation Electrodes, J. Mater. Chem. (2000), vol. 10, 2838-2841.
A. D. Robertson et al., . . . Intercalation Compounds as Electrodes for Lithium Batteries, J. Mater. Chem., (2001) vol. 11, 113-118.
A.D. Robertson et al. Nonstoichiometric Layered . . . Intercalation Electrodes—A Multiple Dopant Strategy, J. Mater. Chem 2003, vol. 13, 2367-2373.
A.D. Robertson et al., Mechanism of Electrochemical Activity in Li2MnO3, Chem. Mater. (2003) vol. 15, 1984-1992.

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