Manganese dioxide product

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Electrode

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423605, H01M 450, C01G 4502

Patent

active

055320848

ABSTRACT:
The invention relates to the manufacture of manganese dioxide by a chemical process. The resulting product takes the form of gamma manganese dioxide particles characterized by filament-like protrusions of ramsdellite manganese dioxide jutting out from the surface of the particles. The manganese dioxide particles having such features can be manufactured by reacting manganese sulfate with sodium peroxodisulfate in an aqueous solution. The process can be controlled to yield high density manganese dioxide. The manganese dioxide formed in the process can be deposited directly onto the surface of electrolytic manganese dioxide (EMD). The manganese dioxide product is particularly suitable for use as a cathode active material in electrochemical cells.

REFERENCES:
patent: 4277360 (1981-07-01), Mellors et al.
patent: 4959282 (1990-09-01), Dahn et al.
T. Nishimura and Y. Umetsu, Shizen Sozai Gakkai-shi, vol. 107 (Jun. 1991) No. 11, pp. 805-810.
Japanese patent publication (Kokai) Application Sho 53-111429, Sep. 1978.

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