Maintaining protective surfaces on carbon cathodes in aluminium

Electrolysis: processes – compositions used therein – and methods – Electrolytic synthesis – Utilizing fused bath

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205389, 205392, 204243R, 204245, 204294, C25C 308, C25C 314

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active

056184034

ABSTRACT:
A cell for the electrowinning of aluminium by the electrolysis of alumina dissolved in a molten fluoride-based electrolyte comprises a cathode composed of a carbon body having an aluminium resistant aluminium-wettable surface layer containing particulate titanium or other refractory hard metal boride and a bonding material providing a porous layer which contains cathodic molten aluminium. Molten cathodic aluminium external to the aluminium-resistant and aluminium-wettable surface contains refractory hard metal and boron in a total concentration sufficient or just below that sufficient to inhibit dissolution into the molten aluminium of the refractory hard metal boride. Alumina is fed to the cell whereby the required amount of titanium in the aluminium results from the alumina feed while, when boron is not present in a sufficient amount, boron is added to bring the total titanium and boron content to or just below the equilibrium solubility product.

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