Maintaining molecular sieve catalytic activity under water...

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – From nonhydrocarbon feed

Reexamination Certificate

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C585S324000, C585S326000, C585S327000, C585S640000, C585S906000, C585S951000

Reexamination Certificate

active

11285699

ABSTRACT:
The invention is directed to methods for protecting metalloaluminophosphate molecular sieves, particularly silicoaluminophosphate (SAPO) molecular sieves, from loss of catalytic activity due to contact with a gas containing water. The methods of the invention provide procedures that enable activated sieve to contact water vapor, within a certain range of time, temperature, and water partial pressure conditions, before the sieve becomes substantially deactivated.

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M. Briend et al., “Influence of the Choice of the Template on the Short- and Long-Term Stability of SAPO Zeolite,”J. Phys. Chem., vol. 99, pp. 8270-8276, 1995.
M.-H. Simonot-Grange et al., “Contribution to the study of framework modification of SAPO-34 and SAPO-37 upon water adsorption by thermogravimetry,”Thermochimica Acta, vol. 329, pp. 77-82, 1999.
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