Maintaining molecular sieve catalytic activity under water...

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Phosphorus or compound containing same

Reexamination Certificate

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C502S208000

Reexamination Certificate

active

07015174

ABSTRACT:
The invention is directed to methods for protecting metalloaluminophosphate molecular sieves, particularly silicoaluminophosphate (SAPO) molecular sieves, from loss of catalytic activity due to contact with a gas containing water. The methods of the invention provide procedures that enable activated sieve to contact water vapor, within a certain range of time, temperature, and water partial pressure conditions, before the sieve becomes substantially deactivated.

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Briend et al., “Influence of the Choice of Template on the Short-and-Long-Term Stability of SAPO Zeolite,”J. Phys. Chem.,vol. 99, pp. 8270-8276, (1995), no month.
Simonot-Grange et al., “Contribution to the Study of Framework Modification of SAPO-34 and SAPO-37 upon water Adsorption by Thermgravimetry,”Thermchimica Acta,vol. 329, pp. 77-82, (1999), no month.
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