Main chain chromophoric polymers with second order nonlinear opt

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526298, 526312, 526243, 526244, 526245, 526248, 528330, 528331, 528327, 528332, 528335, C08G 63685

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052122697

ABSTRACT:
Processible chromophoric polymers having nonlinear optical properties and wherein the chromophore is present in and is a part of the polymer backbone, including substantially all of the monomer or repeat units, with the dipole moments pointing in the same direction (head-to-tail) along the polymer backbone. Such polymers include phenylene, phenylene vinylene, stilbenylene, phenyl piperdine, and coumarin polymers.

REFERENCES:
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Stenger-Smith J. D. et al. (1990) Polymer Preprints 31(1), 375-376 (Mar. 29, 1990).
Stenger-Smith J. D. et al. (1990) Makromol Chem., Rapid Commun. 11(4), 141-144 (rec'd Jun. 5, 1990).
Hoover, J. M. et al. (1991) Polymer Preprints 32(1), 197-198 (Published Mar. 21, 1991).
Kohler, W. et al. (1991) Macromol. 24(16) 4589-4599.
J. Am. Chem. Soc. 1989, 111, 7554-7557, H. E. Katz & M. L. Schilling, "Head to Tail Assemblies of Bipolar", Piperazine Linked Chromophores: Synth. X.sub.- Ray, Structure, & Dielectric Characterization, Sep. 28, 1988.
Ber. Bunsenges. Phys. Chem. 91, 1304-1310 (1987), C. S. Willand and D. J. Williams, "Nonlinear Optical Properties of Polymeric Materials".

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