Magnetic separation of old from new equilibrium particles by mea

Mineral oils: processes and products – Chemical conversion of hydrocarbons – With preliminary treatment of feed

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208 52CT, 208253, 208149, 208152, 502 5, 502 21, C10G 5904, B01J 3734, B01J 2034, B01J 3872

Patent

active

051980983

ABSTRACT:
An improved catalytic process for heavy hydrocarbon conversion, (usually, but not necessarily, in the presence of nickel and vanadium on the catalyst and in the feedstock.) to produce lighter molecular weight fractions. Manganese, which has paramagnetic properties, is added so it progressively accumulates on aged catalyst, and enhances magnetic separation of aged catalyst, to increase activity and improve selectivity of remaining catalyst which is recycled. Manganese acts as a "magnetic hook" to separate more magnetic, older, less catalytically active and less selective, higher-metals-containing catalyst particulates from less-magnetically-active, lower-metal-containing, more catalytically active and selective catalysts fractions, which are then recycled back to the unit.

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"Fluid Dynamics and Science of Magnetic Liquids", R. E. Rosensweig, Advances in Electronics and Electron Physics, vol. 48 (1979) pp. 103-199, Academic Press.

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