Magnetic material for magnetic refrigeration and method for...

Metal treatment – Stock – Magnetic

Reexamination Certificate

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C062S003100, C062S003200, C062S003700, C062S006000, C062S914000, C148S306000, C148S307000

Reexamination Certificate

active

07063754

ABSTRACT:
The magnetic material for magnetic refrigeration according to the present invention has an NaZn13-type crystalline structure and comprises iron (Fe) as a principal element (more specifically, Fe is substituted for the position of “Zn”) and hydrogen (H) in an amount of 2 to 18 atomic % based on all constitutional elements. Preferably, the magnetic material for magnetic refrigeration preferably contains 61 to 87 atomic % of Fe, 4 to 18 atomic % of a total amount of Si and Al, 5 to 7 atomic % of La. The magnetic material for magnetic refrigeration exhibits a large entropy change in a room temperature region and no thermal hysteresis in a magnetic phase transition. Therefore, when a magnetic refrigeration cycle is configured using the magnetic material for magnetic refrigeration, a stable operation can be performed.

REFERENCES:
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patent: 4332135 (1982-06-01), Barclay et al.
patent: 5060478 (1991-10-01), Fukamichi
patent: 5743095 (1998-04-01), Gschneidner, Jr. et al.
patent: 6668560 (2003-12-01), Zimm et al.
patent: 6676772 (2004-01-01), Saito et al.
patent: 2004/0149357 (2004-08-01), Kakimoto et al.
patent: 2004/0231338 (2004-11-01), Saito et al.
ASM Handbook Formerly 9th Edition, Metals Handbook, 1985 pp. 8 and 9.
C. Zimm, et al., Advances in Cryogenic Engineering, vol. 43, pp. 1759-1766, “Description and Performance of a Near-Room Temperature Magnetic Refrigerator”, 1998.

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