Magnesium-group VIII transition metal carbonyl and substituted c

Details Magnesium-group VIII transition metal carbonyl and substituted c Magnesium-group VIII transition metal carbonyl and substituted c

1973-11-27

1976-07-06

Jiles, Henry R.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603461M, 260270R, 260429CY, 260429R, 260439CY, 260439R, 260604HF, 260632HF, 260666B, 252431R, 252431N, 252431P, C07D30704

Patent

active

039681289

ABSTRACT:
The preparation of novel compounds of the general formula B.sub.x Me(M).sub.2 is described; wherein B is a Lewis base, x is an integer 1 through 4, Me is a Group IIA metal, and M is a transition metal carbonyl or a substituted transition metal carbonyl group. These compounds are shown to have utility as catalysts for hydrogenation, butadiene oligomerization, carbonylation, isomerization and hydroformylation. In a preferred embodiment the tetrakis tetrahydrofuran adduct of the magnesium-cobalt phosphine substituted carbonyl complex is shown to effectively catalyze the hydroformylation of 1-hexene.

REFERENCES:
hieber et al., (I) Zeitschrift fur Anorganische and Allegemeine Chemie, Mar. 1962, vol. 314, pp. 125-143.
Burlitch et al., Journal of Organometallic Chem. (1969) vol. 19, pp. 21-23.
Hieber et al., (ii), Chem. Ber. (1961) vol. 94, pp. 1417-1425.

Affiliated with

Also associated with

Rating

Magnesium-group VIII transition metal carbonyl and substituted c does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Magnesium-group VIII transition metal carbonyl and substituted c, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Magnesium-group VIII transition metal carbonyl and substituted c will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-1533169