Magnesium dichloride-ethanol adducts and catalyst components...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S348000, C526S124300, C502S103000, C502S115000, C502S125000

Reexamination Certificate

active

07060763

ABSTRACT:
The present invention relates to a MgCl2.mEtOH adduct in which m is from 2.5 to 3.2 optionally containing water up to a maximum of 1% wt based on the total weight of the adduct, characterized by a DSC profile in which the highest melting Temperature (Tm) peak is over 109° C. and has an associated fusion enthalpy ( H) of 103 J/g or lower. Catalyst components obtained from the adducts of the present invention are capable to give catalysts for the polymerization of olefins characterized by enhanced activity with respect to the catalysts prepared from the adducts of the prior art.

REFERENCES:
patent: 4215013 (1980-07-01), Loontjens
patent: 4399054 (1983-08-01), Ferraris et al.
patent: 6127304 (2000-10-01), Sacchetti et al.
patent: 0 395 083 (1990-10-01), None
patent: 0395083 (1990-10-01), None
patent: 59210906 (1984-11-01), None
patent: 9844009 (1998-10-01), None
Database CA Online; Chemical Abstracts Service, Columbus OH, Mitsui Toatsu Chemicals, Inc., Japan; “Polymerization of alpha-olefins;” retrieved from STN; Database accession No. 102:132653; XP002254446.
Database CA Online; Chemical Abstracts Service, Columbus OH, Xiaoyu Hong et al; “Preparation of spherical MgC12-supported catalyst by spraying for propylene polymerization;” retrieved from STN; Database accession No. 121:206070; XP002254447.
Database CA Online; Chemical Abstracts Service, Columbus OH, Feng-Lou Zou et al; “FTIR study on the preparation of supported catayst for propylene polymerization;” retrieved from STN; Database accession No. 131:243659; XP002254448.
T. Garoff et al., “The influence of water of crystallization on the performance of a Ziegler-Natta catalyst in propylene polymerization;” Transition Met. Organomet. Catal. Olefin Polym., Proc. Int. Symp.; Editors: W. Kaminsky, H. Sinn; Publisher: Springer, Berlin, Fed. Rep. Ger.; p. 198-199 (1987).

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