Macromolecular monomers from living polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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525340, 525191, 525193, 525195, 525196, 525242, 525248, 525250, 525276, 525271, 525286, 525288, 525292, 525340, 526173, 526240, 526242, 526346, C08F 3008, C08F23620

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051049520

ABSTRACT:
A new class of macromolecular monomers (hereinafter called "macromonomers") comprises the polymerized product of at least one of an ethenylarene and a conjugated diene monomer, the product having a terminal omega-alkenyl group of at least four carbon atomes. The novel macromonomer can be copolymerized with ethylene and alpha-olefin monomers to form graft copolymers having pendant side-chains. The graft copolymers are useful as coating and molding compositions. The macromonomers can be useful as coatings on chromatographic supports for analytical and preparative separation of chemical mixtures.

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