Macromers of vinylidene fluoride. Acrylate-terminated poly(vinyl

Details Macromers of vinylidene fluoride. Acrylate-terminated poly(vinyl Macromers of vinylidene fluoride. Acrylate-terminated poly(vinyl

1992-04-07

1993-03-16

Schofer, Joseph L.

Synthetic resins or natural rubbers -- part of the class 520 ser

Synthetic resins

Mixing of two or more solid polymers; mixing of solid...

C08F25908

Patent

active

051945088

ABSTRACT:
Poylmers prepared from vinylidene fluoride having controlled molecular weights and sulfate end groups are described. The sulfate end group can be displaced with acrylic-type acids to produce the corresponding acrylate terminated poly(vinylidene fluoride) macromolecular monomers. These macromers can be copolymerized with acrylates that give rubbery homopolymers to form thermoplastic elastomers.

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An article entitled "Chain Microstructure of Poly(vinylidene fluoride) by 282 MHz .sup.19 F-NMR Spectroscopy" from Macromol. Sci.-Chem., 1989, A26, Fu-Tyan Lin and Fu-Mei Lin pp. 1-16.
An article entitled "Kinetics and Mechanism of Oxidants by Peroxydisulfate" by D. A. House from Chem. Rev., 1961, 185-203.
An article entitled "Synethesis of a Poly(Vinylidene Fluoride) Macromonomer" by J. Oku, R. J. H. Chan, H. K. Hall, Jr., and O. R. Hughes from Polymer Bulletin 1986, 16, 481-485.
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