Macrocyclic tetramers having columnar tridimensional mesophases

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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2604105, 428001, 350330, C07C 6976, C09F 0508

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active

049182170

ABSTRACT:
Octa-substituted derivatives of the macrocyclic tetramers obtained by condensation of resorcinol with an alkyl aldehyde, wherein the sutstituents are alkanoyl, p-alkylbenzoyl, and p-alkoxybenzoyl chains. These substituted tetramers show stable, tridimensional, columnar type mesophases wherein the crystalline lattice is formed with the central macrocyclic rings stacked one on another according to ordered columns, each ring being surrounded with alkyl chains in the melted state.

REFERENCES:
Hoegberg, A. G., Sverker, J. Org. Chem. 45(22), 4498-500, 1980.

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