Lyophilized or precipitated cephalosporin zwitterion and salt co

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Heterocyclic carbon compounds containing a hetero ring...

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540222, A61K 31545, C07D50146

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active

048086177

ABSTRACT:
Amorphous solid formed by lyophilization or cosolvent precipitation of an aqueous solution of 7-[.alpha.-(2-aminothiazol-4-yl)-.alpha.-(Z)-methoximinoacetamido]-3-[(1-m ethyl-1-pyrrolidinio)-methyl[-3-cephem-4-carboxylate zwitterion and a salt or mixture of salts from a selected particular group is a broad spectrum antibiotic composition and has better temperature stability at least up to 45.degree. C. than the zwitterion. The salt is one wherein the cation is selected from the group consisting of sodium, lithium, calcium, and magnesium and the anion is selected from the group consisting of chloride, bromide, and iodide. The molar ratio of zwitterion to salt ranges from about 0.5:1 to about 2:l.

REFERENCES:
patent: 3953439 (1976-04-01), Gleason
patent: 4104391 (1978-08-01), Cise
patent: 4406899 (1983-09-01), Aburaki et al.
patent: 4604386 (1986-08-01), Spry
Kessler et al., "Comparison of a New Cephalosporin, BMY-28142, with Other Broad-Spectrum .beta.-Lactam Antibiotics", Antimicrobial Agents and Chemotherapy, vol. 27, No. 2, pp. 207-216, Feb. 1985.

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