Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides
Reexamination Certificate
1999-10-18
2001-06-26
Kopec, Mark (Department: 1751)
Compositions
Inorganic luminescent compositions
Compositions containing halogen; e.g., halides and oxyhalides
C252S30140H, C313S463000
Reexamination Certificate
active
06251304
ABSTRACT:
BACKGROUND OF THE INVENTION
The invention relates to a luminescent material having a fundamental lattice consisting of an inorganic crystalline compound, which material comprises at least 1 mol % of gadolinium, at least 0.1 mol % of an activator chosen from the group of transition metals and rare earths, and at least 0.1 mol % of a sensitizer.
A luminescent material of this type is known from Netherlands patent application 186707. In the known luminescent material, the sensitizer is chosen from the group of lead, antimony and bismuth, and the activator is chosen from the group of manganese, terbium and dysprosium. The inorganic crystalline compound and the concentrations of sensitizer and gadolinium are chosen to be such that, if no activator is present in the material but comprises only a sensitizer and gadolinium, the material has the characteristic line emission of gadolinium in the range of 310 nm to 315 nm upon excitation by UV radiation at a wavelength of approximately 254 nm. In other words, upon excitation of the material, an energy transfer from the sensitizer to gadolinium takes place. If, as in the known luminescent material, the material comprises an activator in addition to a sensitizer and gadolinium, an efficient transfer of energy also takes place from gadolinium to the activator, even at a relatively low concentration of the activator. Such a low concentration of the activator renders the luminescent material relatively inexpensive. Moreover, at such a low concentration of the activator, there is little concentration quenching so that a high luminous flux can be obtained. A drawback of the known luminescent material is, however, that the quantum efficiency is limited in that only one visible photon is generated for each exciting UV photon.
SUMMARY OF THE INVENTION
It is an object of the invention to provide a luminescent material having a relatively high quantum efficiency.
According to the invention, the sensitizer is erbium and in that the material, if not activated but only sensitized, has the characteristic line emission of gadolinium in the range of 310 nm to 315 nm upon excitation by UV radiation at a wavelength in the wavelength range of 100 nm to 195 nm. The presence of the characteristic line emission of gadolinium, if the material does not comprise any activator but only sensitizer and gadolinium, means that energy transfer takes place from erbium to gadolinium upon excitation.
It has been found that, if a luminescent material according to the invention is excited with UV radiation of approximately 150 nm, visible light is generated by the activator as well as by the sensitizer. This is a result of the fact that at least a part of the Er
3+
ions present in the luminescent material and having absorbed an UV photon transfers the excitation energy in two steps. The
2
F
7/2
level, or the 4f
10
5d level of the Er
3+
ion is excited by the exciting radiation. By means of resonance energy transfer, a part of the energy which is absorbed by the Er
3+
ion is transferred to gadolinium, such that the
6
D
j
level or the
6
I
j
level of a Gd
3
+ ion situated in the ambience of the Er
3+
ion is excited. The energy remaining at the Er
3+
ion is predominantly transferred in that the Er
3+
ion drops back from the
4
S
3/2
level to the fundamental state while emitting a green photon. The energy present at the Gd
3+
ion is transported to an activator ion by means of energy migration via a number of Gd
3+
ions. The energy is transferred to the activator ion which subsequently drops back to the fundamental state while emitting a visible photon. Since at least a part of the exciting photons is converted into two visible photons, it is possible to achieve a quantum efficiency of more than 100% with a luminescent material according to the invention. Due to the efficient energy transfer by gadolinium, the concentrations of sensitizer and activator can be chosen to be such that the sensitizer ions are spatially separated from the activator ions so that quenching due to cross-relaxation in sensitizer-activator pairs is prevented and the quantum efficiency is relatively high.
Satisfactory results have been found for luminescent materials according to the invention, in which the activator comprises one or more of the elements from the group of manganese, samarium, europium, gadolinium, terbium, dysprosium, holmium and thulium.
Preferably, the concentration of erbium is in the range of 0.1 mol % to 5 mol % and the concentration of the activator is in the range of 0.1 mol % to 1 mol %.
Satisfactory results have been obtained for luminescent materials according to the invention, which, in addition to erbium, gadolinium and the activator(s), also comprise at least one element chosen from the group of yttrium, scandium and lanthanum. These three elements are relatively inexpensive so that the luminescent material may be relatively inexpensive by making use of one or more of these elements. It has also been found that the location of the maximum of the absorption band of the luminescent material is influenced by these elements, so that addition of one or more of these elements renders it possible to obtain a good overlap of the absorption band of the luminescent material with the emission band of the excitation source. It has further been found that the presence of fluorine influences the location of the 4f
10
5d level of the Er
3+
ion in such a way that a favorable absorption behavior of the luminescent material is obtained.
Satisfactory results have been achieved with luminescent materials according to the invention in which the fundamental lattice is constituted by LiGdF
4
in which gadolinium may be partly replaced by at least one element chosen from the group of yttrium, scandium and lanthanum.
Luminescent materials according to the invention are very suitable for use in the luminescent screen of a discharge lamp, more particularly a discharge lamp provided with a gastight lamp vessel comprising xenon. A xenon discharge produces relatively much UV radiation in a wavelength range which is very suitable for exciting a luminescent material according to the invention.
These and other aspects of the invention are apparent from and will be elucidated with reference to the embodiments described hereinafter.
REFERENCES:
patent: 3599109 (1971-08-01), Guggenheim
patent: 3891852 (1975-06-01), Bollen et al.
patent: 5891361 (1999-04-01), Kane
patent: 186707 (1979-09-01), None
patent: 97/46488 (1997-12-01), None
Meijerink Andries
Wegh René T.
Faller F. Brice
Kopec Mark
U.S. Philips Corporation
LandOfFree
Luminescent material does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Luminescent material, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Luminescent material will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-2481840